Thanks for all your answers (even though they're all way over my head). Um, actually the K I was referring to in the original post was the equilibrium constant as per: According to Wikipedia: However, in our high school Chemistry class we were told explicitly that, although pressure and volume could effect the position of equilibrium (shift it left or right), only changes in pressure would effect K. This is the bit I don't understand, as per my original post. Sorry for being daft if all your answers above did actually answer my question.